SAKAI CHEMICAL INDUSTRY CO., LTD.

PRODUCT & SERVICE

COSMETIC RAW MATERIALS

Sunscreen and skincare products utilizing the newest nanotechnology contribute to health and
beauty.

Thanks to our long-standing, ultrafine, high-purity and shape-control technology, our Titanium dioxide, barium, and zinc products are used to develop UV-blocking, easy spreading foundations, sunscreen products, and skincare products. Watch the video below to learn more about Sakai Chemical Industry’s SDG initiatives based on fine particle zinc oxide.

PRODUCT LIST

Titanium Dioxide

■Overview

Titanium dioxide is used in sunscreen and skincare products for its dual functions of excellent UV-B shielding and transparency.

Microfine Titanium Dioxide STR Series (Powder)

Provides effective shielding from UV-B rays while maintaining high transparency. Surface activity is successfully suppressed thanks to precise surface treatments.

Grade

Product Name Primary particle size(nm) INCI name Features and Applications
STR-100N 15 Titanium dioxide Non-coated grade
STR-100A-LP 15 Titanium dioxide
Hydrated sillica
Aluminum hydroxide
Hydrogen dimethicone
Standard
STR-100C-LP 15 Titanium dioxide
Aluminum hydroxide
Hydrogen dimethicone
Standard
STR-100W-LP 15 Titanium dioxide
Hydrated sillica
Hydrogen dimethicone
Standard
STR-100C-LF 15 Titanium dioxide
Aluminum hydroxide
Stearic acid
Fatty acid-treated grade
STR-100W-OTS 15 Titanium dioxide
Hydrated sillica
Triethoxycaprylysilane
Texture-modified grade
STR-100W(G) 15 Titanium dioxide
Hydrated sillica
UV-A+UV-Bshielding grade
STR-40-OTS 35 Titanium dioxide
Triethoxycaprylysilane
UVA-UVbshielding grade

■STR Series Electron Microscope View and Optical Properties

Different particle sizes demonstrate different properties. For example, STR-40 products offer high UV-A shielding, while STR-100 products offer high transparency.

【STR-100A-LP TEMimage】

Titanium dioxide is densely coated.

【Optical characteristics of STR series】

Microfine Titanium dioxide Dispersion DIS and GT Series

■Overview

Microfine Titanium dioxide STR Series (Liquid Dispersion)

Grade

Product Name Dispersoid(Powder)
composition(wt%)
Dispersion medium Powder grade particle size(nm) Features and Applications
DIS-AB-10W 50 Water STR-100W-LP 15 High SPF、Good feel
O/W Wlayersorientation
GT-10W2 40 Water STR-100W 15 O/W Wlayersorientation
DIS-11A 40 Cyclopentasiloxane STR-100A-LP 15 Standard
W/O Olayersorientation
DIS-12C 45 Cyclopentasiloxane STR-100C-LP 15 W/O Olayersorientation
DIS-OP-10A 50 Ethlhexyl palmitate STR-100A-LP 15 High passivity
O/W Olayersorientation
DIS-TL-10A 50 Isotridecyl isononanoate STR-100A-LP 15 High passivity
O/W Olayersorientation

Pigment-grade Titanium Dioxide MKR Series

Grade

Product Name Particle size(nm) INCI name Features and Applications
MKR-1 200 Titanium dioxide
Hydrogen dimethicone
Hydrophilic.Aluminum-free. Can be used in water-based formulations.
MKR-1S 200 Titanium dioxide
Hydrogen dimethicone
Hydrophobic. Aluminum-free.
Reduced photocatalytic activity in comparison to compatitors'products.

Inquiries

Cosmetic Innovation Department
TEL +81-3-5823-3725

Zinc Oxide

■Overview

Zinc oxide is used in sunscreen and skincare products for its dual functions of excellent UV-A shielding and transparency.

Ultrafine Zinc Dioxide FINEX Series (Powder)

Provides effective shielding from UV-A rays while maintaining high transparency.

Grade

Product Name Primary particle size(nm) INCI name Features and Applications
FINEX-50 20 Zinc oxide Non-coated grade
FINEX-30 35 Zinc oxide Non-coated grade
FINEX-50LP 20 Zinc oxide
Hydrogen dimethicone
Standard
FINEX-33W 35 Zinc oxide
Hydrated sillica
Passivated grade
FINEX-52W-LP2 20 Zinc oxide
Hydrated sillica
Hydrogen dimethicone
Passivated grade
FINEX-33W-LP2 35 Zinc oxide
Hydrated sillica
Hydrogen dimethicone
Passivated grade
FINEX-50S-LP2 20 Zinc oxide
Hydrogen dimethicone
High-transparency grade
FINEX-30S-LPT 35 Zinc oxide
Hydrogen dimethicone
Low-viscosity grade
FINEX-50-OTS 20 Zinc oxide
Triethoxycaprylysilane
Texture-modified grade
FINEX-30-OTS 35 Zinc oxide
Triethoxycaprylysilane
Texture-modified grade

■Optical characteristics of FINEX Series

Characteristics vary based on the particle size.FINEX-25 has high UVA shielding performance,and FINEX-50 has high transparency.

【FINEX-52W-LP2 TEM image】

Zinc oxide is densely coated by a sillica layer.

【Total light transmittance】

■High-Density Silica Coating (Inactive Grade)

Higher silica processing volume provides stronger suppression of photocatalytic activity.

high-density sillica coating

Different silica processing offers different activities (Vaseline discoloration test)

Ultrafine Zinc oxide Dispersion DIF Series

■Overview

A liquid dispersion of the Ultrafine Zinc Oxide FINEX series.

Grade

Product Name Dispersoid(Powder)
composition(wt%)
Dispersion medium Powder grade particle size(nm) Features and Applications
DIF-AB-33W 60 Water FINEX-33W-LP2 35 High transparency、Good feel
O/W Wlayersorientation
DIF-3ST2 50 Cyclopentasiloxane FINEX-30S-LPT 35 Standard
W/O Olayersorientation
DIF-AW4 50 Cyclopentasiloxane FINEX-52W-LP2 20 High transparency
W/O Olayersorientation
DIF-3W4 60 Cyclopentasiloxane FINEX-33W-LP2 35 High UV shielding
W/O Olayersorientation
DIF-5CS 50 Cyclopentasiloxane FINEX-50-OTS 20 Good feel
W/O Olayersorientation
DIF-OP-3W 70 Ethlhexyl palmitate FINEX-33W-LP2 35 High passivity
O/W Olayersorientation
DIF-TL-3W 70 Isotridecyl isononanoate FINEX-33W-LP2 35 High passivity
O/W Olayersorientation

Hexagonal Flake-shaped Zinc oxide XZ Series

■Overview

Hexagonal flake zinc oxide is available in different particle sizes to match a wide range of sun care and cosmetic product applications.

Grade

Product Name Particle size(nm) Thickness(nm) INCI name Features and Applications
XZ-100F-LP 100 30 Zinc oxide
Hydrogen dimethicone
High UV shielding effect.
XZ-300F-LP 300 100 Zinc oxide
Hydrogen dimethicone
Booster effect to increase SPF
Can be also used as a white pigment.
XZ-1000F-LP 1000 290 Zinc oxide
Hydrogen dimethicone
Good skin feel and the ability to produce optimal whiteness enable it to be substituted for pigment-grade titanium dioxide.
XZ-3000F-LP 3000 750 Zinc oxide
Hydrogen dimethicone
Best skin feel in the series.
XZ-1000FST 1000 80 Zinc oxide The thinning has improved UV shielding ability and feel.

*Non-coated items also included in lineup

Spherical Zinc oxide Formed by Flake-shaped Particles CANDY ZINC

Grade

Product Name Particle size(nm) INCI name Features and Applications
CANDY ZINC 1000 1000 Zinc oxide
Polysordate 80
Has a good skin feel while also offering high ultraviolet shielding and sebum absorption effect.

*Non-coated items also included in lineup

■Pressure resistance test

2MPa particles keep their shape even after pressing at 2MPa.

《Measurement conditions》

2g of test samples were placed in a 35mm diameter ring and compacted.

■Sebum absorption of CANDY ZINC

CANDY ZINC has a high sebum absorption effect.

《Mesurement method》

  1. Artitical sebum was mixed with test samples in centrifuge tubes,in the ratios shown above.
  2. After being left to stand for 30 minutes,the mixtures were centrifugally separated,and the separated solvents were collected.
  3. The solvents were measured using FT-IR to enable calculation of the peak area of 2045-2875 cm-1(C-H symmetric stretch vibration) derived form sebum.
  4. Calibration curves were formulated in order to calculate the sebum absorption rate.The artificial sebum was produced by mixing oleic acid,squalene,and olive oil in a ratio of 1:2:2

LARGE PARTICLE ZINC OXIDE LPZINC series

Grade

Product Name Particle size(μm) INCI name Shape
LPZINC-2 2 Zinc oxide amorphous
LPZINC-5 5 Zinc oxide amorphous
LPZINC-11 11 Zinc oxide amorphous
LPZINC-30S 40 Zinc oxide spherical
LPZINC-50S 70 Zinc oxide spherical

*Coated items also included in lineup

【LPZINC-11】

【LPZINC-30S】

■LPZINC Features

  1. Low average friction factor, great texture.
  2. Anti-odor and anti-bacterial properties.
  3. Same sebum adsorption effect as CANDY ZINC.
  4. Excellent thermal conductivity, suitable for high-density filling and blending with a variety of plastics.

Inquiries

Cosmetic Innovation Department
TEL +81-3-5823-3725

Barium

Flake-shaped barium sulfate H

Grade

Product Name Particle size(μm) INCI name Characteristics
H 7 Barium sulfate Offers matte finish.
HM 10 Barium sulfate Good balance of matte and luster finish.
HL 15 Barium sulfate Offers more luster than HM.
HG 20 Barium sulfate The grade with the most shiny luster finish.
H-LFM 7 Barium sulfate
Magnesium myristate
Matte finish with good smoothness.
HG-LFP 20 Barium sulfate
Magnesium hydroxide
Palmitic acid
Luster finish with good smoothness.

*Coated items also included in lineup

■Long-Lasting Soft Focus Effect of H-LFM Lamellar Barium Sulfate

Lamellar Barium sulfate has a higher soft-focus effect than mica and has proven effective for long-lasting makeup applications.

《Evaluation Method》

First, after face washing, apply skin lotion and milky lotion and allow them to soak in for 15 minutes. Next, apply an appropriate quantity of powder foundation, and quantify the number of spots and pores using a VISIA skin analyzer.

■Comparative data of flake-shaped barium sulfate and other materials

The soft effect of flake-shaped barium sulfate is higher than with other materials.

《Measurement conditions》

0.2g of sample + 0.8g of silicone(PWC = 20 wt%) were dispersed twice with 25 turns at 100 pounds in a Hoover muller,applied to a glass plate with a 1mil applicator,and measured in a haze meter.

Inquiries

Cosmetic Innovation Department
TEL +81-3-5823-3725

Calcium

■Overview

Spherical particles with a uniform particle size provide great texture and a moderate soft-focus effect. Alternative material to plastic beads.

Spherical Calcium Carbonate Calmaru

Grade

Product Name Particle size(μm) INCI name Oil absorption Features and Applications
SCS-M5 5 Calcium carbonate
Sodium metaphosphate
42 ㎖ / 100g(IPM) Offers both excellent soft foucus effect and a high level of press moldability.

■Drop test of molded compound

By blending Calmaru and Flake-shaped barium sulfate H,press formability is improved.

《Measurement conditions》

Samples(10g) were placed in a vessel and molded by pressing at 2MPa for 30sec.The molded compounds were dropped from a height of 10 cm,and the number of cycles until breakage was recorded.

■Soft focus effect of Calmaru after sebum absorption

Even after moistening with sebum,Calmaru does not change color and keeps its soft focus effect.

《Measurement method》

Artifical sebum (0.9g) was mixed with test materials(1.2g),and the powder was checked for color change.The artifical sebum was produced by mixing oleic acid,squalane,and olive oil in a ratio of 1:2:2.

The change in the soft focus effect of the extender pigment was examined using oleic acid,one of the major components of sebum.

Inquiries

Cosmetic Innovation Department
TEL +81-3-5823-3725

Water Repellent Pigment 1, 3-BG Dispersion

DIP(N) Series

Features

・ High-viscosity pastes with water-repellent pigments dispersed in 1, 3-butylene glycol.

・ High viscosity design suppresses pigments subsidence and allows for easy handling.

・ Long-lasting makeup application is improved by mixing water repellent powders in a water phase.

Grade

Product Name Pigment Type Powder
composition
(wt%)
Dispersant 1,3 Butylene Glycol

DIP-T1(N)

Hydrogen dimethicone-treated Titanium dioxide 75% 3.0% 22.0%

DIP-R1(N)

Hydrogen dimethicone-treated red iron oxide 50% 1.5% 48.5%

DIP-Y1(N)

Hydrogen dimethicone-treated yellow iron oxide 60% 2.5% 37.5%

DIP-K1(N)

Hydrogen dimethicone-treated black iron oxide 60% 2.5% 37.5%

【Water dispersibility】

【Long lasting effect】

Inquiries

Cosmetic Innovation Department
TEL +81-3-5823-3725

Cosmetic Inorganic Fluorescent Materials

Cosmetic Inorganic Fluorescent Materials Lumate® Series

Characteristics

◯Absorbs harmful UV rays,transforming them to visible light to shine.

◯Composed of elements used in cosmetic materials.

◯Green (Lumate®G) corrects reddish hues,red (Lumate®R) gives skin a healthy look,and blue (Lumate®B) gives it a translucent look.

◯Various shining colors including white can be produced by combining the three Lumate products.

◯Lumate®G(Particle size 2.5μm)

INCI name:Zinc oxide

【SEM image】

【Emission / excitation spectra】

【Particle size distribution】

◯Lumate®R(Particle size 3.0μm)

INCI name:Magnesium / Manganese / Titanium Oxide

【SEM image】

【Emission / excitation spectra】

【Particle size distribution】

◯Lumate®B(Particle size 8.0μm)

INCI name:Calcium Cerium Phosphate

【SEM image】

【Emission / excitation spectra】

【Particle size distribution】

Inquiries

Cosmetic Innovation Department
TEL +81-3-5823-3725

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